Sulfonation Mechanism of Fatty Acid Methyl Ester with Sulfur Trioxide

FATTY ACID METHYL ESTER PROFILING OF Enterococcus and E

Automated determination of fatty acid methyl ester and cis/trans methyl ester composition of fats and oils.

The determination of the fatty acid composition (as methyl esters, FAMEs) of fats and oils and their cis/trans (CTME) distribution requires a simple, but manual and time-consuming sample preparation. The so-called BF3 method is often the preferred procedure. Because FAME/CTME analyses are encountered very frequently in the food industry, an automated, robot-based alternative is proposed which u...

Hydrogenation of fatty acid methyl ester to fatty alcohol at supercritical conditions

Hydrogenation of various types of oleochemicals is a major unit operation in industry. Natural fatty alcohols are important raw materials for surfactants and lubricants and can be produced by catalytic hydrogenation of fatty acid methyl esters (FAME). Commercial multiphase processes are necessarily operated at high pressures and high hydrogen-to-ester mole ration owing to low solubility of hydr...

Repeated production of fatty acid methyl ester with activated bleaching earth in solvent-free system

Synthesis of sulfate esters of lithocholic acid, glycolithocholic acid, and taurolithocholic acid with sulfur trioxide-triethylamine.

The facile synthesis of lithocholic acids sulfates by a procedure that produced the desired products in over 90% yield is described. Lithocholic acid sulfate and glycolithocholic acid sulfate were synthesized by reacting lithocholic acid or glycolithocholic acid with sulfur trioxide-triethylamine complex in dimethylformamide for 0.5-1 hr. Taurolithocholic acid sulfate was obtained by conjugatin...